Originally Posted by
Photolysis
Physically impossible, according to the laws of thermodynamics.
At absolute zero, the atoms would be at the lowest energy state, but they would still have some energy (the zero point energy). This is energy that cannot be taken away.
Molecules wouldn't fall apart simply because they would have no energy to do so. Breaking stuff requires energy. Stuff at absolute zero would be a solid. And yes, Van der Waal forces would definitely still apply.
Electrons don't orbit atoms; atoms are not really like a model of the solar system despite what it often taught to students beginning to learn science. They're essentially thought of as a field of charge and the energy state is basically the probability of it being in a certain region around the atom.