do you mean it is physically impossible, or impossible because we dont have the technology yet?
Physically impossible, according to the laws of thermodynamics.

i was also thinking, if absolute zero does stop all movement/vibrations, then does that mean that electrons stop orbiting? because if it does, then wouldnt that mean that the van der waals forces in a covalent molecules would fall apart from each other? which would make what ever it is just break up or turn to liquid or gas or whatever (which would be the opposite of what would be expected since it would be below its melting point.
At absolute zero, the atoms would be at the lowest energy state, but they would still have some energy (the zero point energy). This is energy that cannot be taken away.

Molecules wouldn't fall apart simply because they would have no energy to do so. Breaking stuff requires energy. Stuff at absolute zero would be a solid. And yes, Van der Waal forces would definitely still apply.

Electrons don't orbit atoms; atoms are not really like a model of the solar system despite what it often taught to students beginning to learn science. They're essentially thought of as a field of charge and the energy state is basically the probability of it being in a certain region around the atom.