(NOTE: when listening/watching to these videos please have on stereo headphones.)
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I recommend the "Between Worlds", and "Cloudscapes" videos to start off...
As for strictly Binaural Beats, I recommend trying out the "Alpha", "Theta", and "Delta" brainwave inducing videos listed on the page before moving on to more intense ones.
Alpha - Total Relaxation/Creativity
Delta - Resorative Sleep/Deep Meditation/Intuition
Theta - Deep Learning/Strengthen Memory
The easiest way of applying stimulus to the brain is via ears and eyes. Since humans cannot hear sounds low enough to be useful for brain stimulation, special techniques must be used. One such special technique used is called binaural beats.
If the left ear is presented with a steady tone of 495Hz and the right ear a steady tone of 505Hz, these two tones combine in the brain. The difference, 10Hz, is perceived by the brain and is a very effective stimulus for brainwave entrainment. This 10Hz is formed entirely by the brain. When using stereo headphones, the left and right sounds do not mix together until in your brain. The frequency difference, when perceived by brain this way, is called a binaural beat.
The patented Hemi-Sync® process has been refined with over 40 years of research and development. Ongoing experimentation, data collection and analysis are conducted at The Monroe Institute's laboratory facilities to demonstrate the correlations between subjective experiential reports and objective electronic measurements.
Such research is indispensable in revealing the influence of specific Hemi-Sync sound patterns on consciousness. Over the years, these efforts have resulted in the development of scores of individual products for specific applications such as focused attention, stress reduction, meditation, sleep enhancement, and pain control, to name a few.
Thoughts? 
[Edit: It's times like these that I'm glad I have the award winning Beyerdynamic DT-880 Headphones]
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