Ninja's right, B-complex tends to energize the mind. It's timing is to be taken before bed. If it's causing you issues in falling asleep, then you can safely take 0.5mg of melatonin to help you fall back to sleep (which is something I normally do). A low amount like that won't suppress the REM cycle.
Alternatively, you can either take L-theanine (200mg should do) or DHEA (not sure on dosage). DHEA is the hormone we produce later in the night to help keep us asleep, as we stop producing melatonin about 3-4 hours into sleep.
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